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What is the chemical difference between soap and detergent?
Posted July 30, 2021

Answer

Although soap and detergent are often referred to interchangeably, they are in fact chemically very different from each other.

Soap

  • Is a potassium or sodium salt of a carboxylic acid with a long aliphatic chain attached to it
  • Is hydrophilic due to the presence of carboxylate at the end of its molecular structure
  • Derived from natural sources, usually through saponification of vegetable oils and animal fats
  • Is biodegradable and environment-friendly
  • Not effective in hard water or saline water

Detergent

  • Is a potassium or sodium salt of a long alkyl chain ending with a sulfonate group
  • Is soluble in hard water because the sulfonate group does not attach itself to the ions present in water
  • Is a synthetic derivative and not easily biodegradable
  • Do not lose their effectiveness in hard water or saline water