Ligands are ions or molecules that form coordination compounds or coordination complexes by binding to the central metal atom or ion. There are 9 types of ligands based on their denticity (the number of binding sites with the central metal atom)
- Monodentate ligands bind the metal atom or ion at only one place. They are also known as one-toothed ligands. Examples - Bromide ion, fluoride ion, ammonia, water, carbon monoxide
- Bidentate ligands bind with the same central metal atom or ion through two different donor atoms. They are also known as chelating ligands. Examples - Acetylacetonate ion, Oxalate ion, Phenanthroline, Dimethylglyoxime
- Tridentate ligands bind three lone pairs of electrons to the central metal atom or ion. Examples - Diethylenetriamine
- Tetradentate ligands bind four lone pairs of electrons to the central metal atom or ion. Examples - Triethylenetetramine, Nitrilotriacetato
- Pentadentate ligands, which have five donor atoms, are rare because of ring strain. Example - Ethylenediaminetriacetato.
- Hexadentate ligands have six donor atoms. Example - Ethylenediaminetetraacetate
- Ambidentate ligands have more than one potential donor atom but only one of them at a time can bond with the central metal atom. Example - Thiocyanate ion (NCS–) which can bind to the central metal atom or ion with either nitrogen or sulfur atoms. NO2– and SCN–.
- Bridging ligands have lone pairs of donor atoms that bind to two or more metal atoms. Examples- Hydroxide, Chloride, Oxide, Carbonyl
- Cyclic or ring ligands have cyclic structures with several lone pairs of atoms available for donation. Chelates that are formed with metal atoms are more stable than non-cyclic complexes. Examples – Vitamin B12, Chlorophyll, Hemoglobin